The Cyclic Voltammetry ofp-Tropoquinone Acetals

Cyclic Voltammetry

Cyclic Voltammetry of Auranofin

The oxidative behavior of Auranofin, 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranosato- S(triethylphosphine)gold(I), was investigated by using cyclic voltammetry (CV) in 0.1 M Bu(4)NPF(6)/CH(2)Cl(2) and 0.1 M Bu(4)NPF(4)/CH(2)Cl(2) solutions using Pt working and auxiliary electrodes and a Ag/AgCI reference. CV studies at scan rates from 50-2,000 mV/s and Auranofin concentrations between 1 an...

Synthesis and Bactericidal Activity of Substituted Cyclic Acetals

Bacteria of the genus Azospirillum are among the most studied bacteria, stimulating the growth of plants and capable of associative interaction with many higher plants. They have a high adaptive potential to the negative external influences, like the lack of nutrients, salinity, lack of moisture. Compared with other rhizosphere microorganisms, Azospirillum have sufficiently high resistance to h...

Cyclic acetals as cleavable linkers for affinity capture.

Labeling proteins with biotin is a widely used method to identify target proteins due to biotin's strong binding affinity for streptavidin. Combined with alkyne-azide cycloaddition, which enables the coupling of probes to targeted proteins, biotin tags linked to an alkyne or azide have become a powerful tool for purification and analysis of proteins in proteomics. However, biotin requires harsh...

Cyclic acetals as coinitiators in CQ-induced photopolymerizations

A series of cyclic acetals were investigated with regard to their ability to function as coinitiators in free-radical photopolymerization induced by camphorquinone (CQ). Among these cyclic acetals, the reactivity of 2-hexyl-1,3-benzodioxole (HBDO) was the highest, according to the quantum yield of CQ. However, the most efficient coinitiator was l,3-benzodioxolane, which has a reactivity signifi...